改性纳米氮化硅/FKM复合材料的制备和性能研究
改性纳米氮化硅/FKM复合材料的制备和性能研究Preparation and Properties of Modified Nano-silicon Nitride/FKM Composite
作 者：黄劲德 钱家盛 章于川
HUANG Jin-de,QIAN Jia-sheng,ZHANG Yu-chuan（Anhui University,Hefei 230039,China）
机构地区：安徽大学化学化工学院,安徽合肥230039
出 处：《橡胶工业》 CAS 2011年第58卷第10期 586-590页,共5页
China Rubber Industry
基 金：国家科技支撑计划项目（2007BAE22B02）
摘 要：采用甲基丙烯酸六氟丁酯-甲基丙烯酸甲酯-甲基丙烯酸缩水甘油酯三元共聚物对纳米氮化硅进行表面改性,制备改性纳米氮化硅/氟橡胶（FKM）复合材料,并对其性能进行研究。结果表明：改性纳米氮化硅在FKM基体中分散均匀;当改性纳米氮化硅用量为1.5份时,改性纳米氮化硅/FKM复合材料的综合物理性能、耐磨性能、耐热空气老化性能和耐油性能较好。
The nano-silicon nitride was modified by hexafluorobutyl mathacrylate-methyl methacrylate-glycidyl methacrylate terpolymer,the modified nano-silicon nitride/FKM composite was prepared,and its properties were investigated.The results showed that,the modified nano-silicon nitride was uniformly dispersed in FKM matrix;when the addition level of modified nano-silicon nitride was 1.5 phr,the composite possessed better comprehensive physical properties,wear resistance,thermal aging property and oil resistance.
关 键 词：纳米氮化硅 表面改性 氟橡胶 复合材料
nano-silicon nitride surface modification FKM composite
分 类 号：TQ330.383 [工业技术 > 化学工业 > 橡胶工业 > 一般性问题 > 原料与辅助物料 > 补充剂与填充剂] TQ333.93 [工业技术 > 化学工业 > 橡胶工业 > 合成橡胶]
参考文献作者在撰写文献时引用的其他文献，反映本文的背景或依据。 (15篇)张洪雁 曹寿德 王景鹤.高性能橡胶密封材料.北京:化学工业出版社,2007..
Bugani S,Camaiti M, Morselli L,et al. Investigating Morphological Changes in Treated vs. Untreated Stone Building Materials by X-ray Micro-CT. Analytical and Bioanalytical Chemistry,2008,391(4):1343-1350.
Maiti M,Bhowmick A K. Dynamic Viscoelastic Properties of Fluoroelastomer/Clay Nanocomposites . Polymer Engi neering and Science,2007 ,47(11):1777-1787.
Giovedi C,Pino E S,Rossi M R,et al. Electron Beam Irradiation Effects on the Mechanical, Thermal and Surface Properties of a Fluoroelastomer. Nuclear Instruments and Me thods in Physics Research B,2007,45(1):256-259.
Kader M A, Nah C. Influence of Clay on the Vulcanization Kinetics of Fluoroelastomer Nanocomposites . Polymer, 2004,45 (7): 2237-2247.
Valsecchi R, Vigano M, Levi M, et al. Dynamic Mechanical and Rheological Behavior of Fluoroelastomer-organoclay Nanoeomposites Obtained from Different Preparation Method . Journal of Applied Polymer Science, 2006,102 (5) : 4484- 4487.
Gao J M,Gu Z, Song G J, et al. Preparation and Properties of Organo-montmorillonite Fluoroelastomer Nanocomposites . Applied Clay Science,2008,42(1) :272-275.
Maiti M,Bhowmick A K. New Fluoroelastomer Nanocomposites from Synthetic Montmorillonite. Composites Science and Technology,2008,68(1) :1-9.
欧宝立 李笃信.表面修饰纳米SiO2增强增韧聚氯乙烯.复合材料学报,2009,26(1):48-53.
却梅 柴大付 章于川.改性纳米氮化钛/ACM复合材料性能的研究.橡胶工业,2009,56(7):402-405.
Gao B J ,Lei H B,Jiang L D,et al. Studies on Preparing and Adsorption Property of Grafting Terpolymer Microbeads of PEI-GMA/AM/MBA for Bilirubin. Journal of Chromatography B,2007,853(1/2) :62-69.
Qi R R, Chen Z F, Zhou C X. Solvothermal Preparation of Maleie Anhydride Grafted onto Acrylonitrile-butadiene-styrene Terpolymer (ABS) . Polymer, 2005,46 (12) : 4098- 4104.
Xia R,Li M H,Zhang Y C. Synthesis of Tercopolymer BA- MMA-VTES and Surface Modification of Nano-size Si3N4 with This Macromolecular Coupling Agent . Journal of Applied Polymer Science, 2007,107(2) : 1100-1107.
Tai Y L,Qian J S,Zhang Y C,et al. Study of Surface Modification of Nano-SiO2 with Macromolecular Coupling Agent (LMPBg MAH) . Chemical Engineering Journal, 2008, 141(1/3) :354-361.
郭建华 曾幸荣 罗权煜等.FKM2g2VTEO对氟橡胶/硅橡胶共混物的增容作用.高分子材料科学与工程,2009,25(12):92-95.
页:
[1]