超临界CO2辅助PTFE/PP挤出的研究
超临界CO2辅助PTFE/PP挤出的研究STUDY ON EXTRUSION OF PTFE/PP ASSISTED BY SUPERCRITICAL CARBON DIOXIDE
作 者:杜小刚 刘亚青 谢江波 马春
Du Xiaogang, Liu Yaqing, Xie Jiangbo, Ma Chun (Research Center for Engineering Technology of Polymeric Composites of Shanxi Province, North University of China, Taiyuan 030051, China )
机构地区:中北大学山西省高分子复合材料工程技术研究中心,太原030051
出 处:《工程塑料应用》 CAS CSCD 2008年第36卷第2期 35-37页,共3页
Engineering Plastics Application
摘 要:研究了超临界CO2辅助聚四氟乙烯(PTFE)/聚丙烯(PP)共混体系的挤出成型过程。结果表明,超临界CO2辅助挤出成型过程中,超临界CO2对阿FE/PP体系能起到一定的增韧作用,并且超临界CO2作为一种增塑剂,能降低阿FE/PP体系的粘度,改善体系的流动性和加工性。
PTFE/PP extrusion assisted by supercritical carbon dioxide was studied. The results showed that the supercritical carbon dioxide could make the polymer system tougher. As a plasticizer, the supercritical carbon dioxide could reduce apparent viscosity of polymers, improve the rheological property and process ability of polymers.
关 键 词:超临界CO2 聚四氟乙烯 聚丙烯 增韧 降粘
supercritical carbon dioxide, PTFE, PP, toughening, viscosity reduction
分 类 号: TQ028.32 [工业技术 > 化学工业 > 一般性问题 > 化工过程(物理过程及物理化学过程) > 分离过程 > 单相系液态混合物的分离过程] TQ325.4 [工业技术 > 化学工业 > 合成树脂与塑料工业 > 聚合类树脂及塑料]
参考文献作者在撰写文献时引用的其他文献,反映本文的背景或依据。 (6篇)Paulaitis M E, Alexander G C. Reactions in supereritical fluid, a case study of the thermodynamic solvent effects on a dielsalder reaction in supercritical CO2 [ J]. Pure Appl Chem, 1987,59 (1) :61 - 68.
Chaudhary A K, Beckman E T, Russell A T. Rational control of polymer molecular weight and dispersity during enzyme catalyzed polyster synthesis in supercritical fluids [ J ]. J Am Chem Soc, 1995,117(13) :3728 -3733.
Goel S K, Beckman E J. Plasticization of polymethyl methacrylate networks by supercritical carbon dioxide [ J ]. Polymer, 1993,34 (7) :1410 - 1417.
Yan X, Kiran E. Miscibility density and viscosity of poly(dim ethyl siloxane) in supercritical carbon dioxide. Polymer, 1995, 36(25) :4817 -4826.
曹现福 陈鸣才 陈德宏 等.超临界CO2在高分子合成及加工领域的应用.高分子通报,2006,4(5):21-24.
徐佩弘.高聚物流变学及其应用.北京:化学工业出版社,2003.85-88.
页:
[1]