PFSI/PTFE复合膜用于质子交换膜燃料电池的研究

PTFE

PFSI／PTFE复合膜用于质子交换膜燃料电池的研究
耿东森[1] 李培金[2][1]华北科技学院,北京东燕郊101601 [2]北京化工大学材料科学与工程学院,北京100029

摘　要:通过将全氟磺酸溶液加入到胛FE多孔膜中制备了PFSI／PTFE复合膜。SEM的测试结果显示，已有一层均匀的薄的PFSI膜存在于PTFE多孔膜表面，全氟磺酸树脂已均匀地分布到PTFE多孔膜中。实验证明，复合膜的强度和尺寸稳定性都优于单膜；厚度为40μm的复合膜，其电性能与厚度为60μm的单膜接近，复合膜最低膜厚可达20μm。用价格相对便宜的PTFE来部分代替昂贵的全氟磺酸树脂，可以减少全氟树脂的用量，降低质子交换膜燃料电池的制造成本。[著者文摘]

关键词:全氟磺酸树脂 聚四氟乙烯 复合膜 质子交换膜燃料电池
分类号:　TM911.4[著者标引]文献标识码：A文章编号：1672-7169（2009）02-0037-04栏目信息：
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Study on PFSI/PTFE Composite Membrane for Proton Exchange Membrane Fuel CellGENG Dongsen ,LI Peijin 1. Noah China Institute of Science and Technology, Yanjiao Beijing-East 101601 ; 2. College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029AbstractFSI/PTFE composite membranes were prepared by impregnating PFSI solution into porous PTFE films. According to the SEM photomicrographs, a homogeneous thin PFSI film is formed on PTFE film surface, and the PFSI is dispersed in it evenly. The strength and dimension stability of the composite membrane was supeior to that of the homogeneous membrane due to the enforcement of FIFE films. The fuel cell performance of the 40μm thickness composite membrane appeared to be exactly the same as those of the 60μm thickness homogeneous membrane, the lowest thickness of prepared composite membrane is 20μm. As the expensive PFSI resins were replaced by relative lower PTFE, less amount of PFSI was used and PEMFC has much lower prices.[著者文摘]

Key wordsolypertlurosulfonic acid resin ; polytetrafluoroethylene （PTFE） ; composite membrane ; PEMFC