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接枝改性纳米氧化铝填充PTFE复合材料摩擦学性能研究

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    发表于 2012-12-11 21:25:15 | 显示全部楼层 |阅读模式
    接枝改性纳米氧化铝填充PTFE复合材料摩擦学性能研究
    Tribological Properties of PTFE Composites Filled with Grafted Alumina Nanoparticles
    作  者:牛永平 李香燕 张军凯 韩明 张永振

    Niu Yongping, Li Xiangyan, Zhang Junkai, Han ming, Zhang Yongzhen ( Key Laboratory of Materials Tribology, Henan University of Science and Technology, Luoyang 471003, China )

    机构地区:河南科技大学材料摩擦学重点实验室,河南洛阳471003

    出  处:《工程塑料应用》 CAS CSCD 2012年第40卷第7期 5-8页,共4页

    Engineering Plastics Application

    基  金:国家自然科学基金项目(U1034002,51175149)、河南科技大学人才科研基金项目(09001146)

    摘  要:合成了含氟分子链接枝改性纳米氧化铝(A12O3),用接枝改性纳米A12O3,填充聚四氟乙烯(PTFE),采用模压成型法制备了不同接枝改性纳米A1203含量的PTFE/纳米A1203复合材料;在摩擦磨损试验机上考察了接枝改性纳米A12O3对PTFE/纳米A12O3,复合材料摩擦学性能的影响,利用扫描电子显微镜对复合材料的磨损表面进行了微观分析。结果表明,接枝改性纳米A1203填充PTFE复合材料在保持PTFE低摩擦系数的同时,提高了其耐磨损性能。

    Fluorinated polymer chain grafted alumina nanoparticles were synthesized.Polytetrafluoroethylene ( PTFE ) nanocomposites filled with grafted alumina nanoparticles were prepared by compression molding.The effects of grafted alumina nanoparticles on the tribological behavior of the nanocomposites were investigated on a tribometer.The abrasion mechanisms of the nanocomposites were investigated by scanning electron microscopy of the abraded surfaces.The results showed that the addition of grafted alumina nanoparticles maintained low friction coefficient and improved the wear resistance of the nanocomposites.

    关 键 词:聚四氟乙烯 接枝改性纳米A12O3 复合材料 摩擦学性能
    PTFE grafted alumina nanoparticles composites tribological properties
    分 类 号: TQ325.4 [工业技术 > 化学工业 > 合成树脂与塑料工业 > 聚合类树脂及塑料]

    参考文献作者在撰写文献时引用的其他文献,反映本文的背景或依据。 (13篇)[1]Biswas S K, Vijayan K.Friction and wear of PTFE A review [ J ].Wear, 1992,158 ( 1-2 ) : 193-211.
    [2]Aderikha V N, Shapovalova V A.Effect of filler surface properties on structure, mechanical and tribological behavior of PTFE-carbon black composites [ J ] .Wear,2010,268 ( 11-12 ) : 1 455-1 464.
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    [4]Mu Liwen, Chen Jian, Shi Yijun, et al. Durable poly- tetrafluoroethylene composites in harsh environments : Tribology and corrosion investigation [ J . Journal of Applied Polymer Science,2012,124 ( 5 ) : 4307-4314.
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    [7]Krick, B A, Ewin J J, Blackman G S, et al.Environmental dependence of ultra-low wear behavior of polytetrafluoroethylene ( PTFE ) and alumina composites suggests tribochemical mechanisms I J ] .Tribology Intemational, 2012,51 : 4246.
    [8]Blanchet T A, Kandanur S S, Schadler L S.Coupled effect of filler content and countersurface roughness on PTFE nanocomposite wear resistance [ J ].Tribology Letters, 2010,40 ( 1 ) : 11-2 I.
    [9]Vail J R, Burris D L, Sawyer W G.Multifunctionality of single- walled carbon nanotube-polytetrafluoroethylene nanocomposites [ J ] ,Wear,2009,267 ( 1-4 ) : 619-624.
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    [11]牛永平 韩明杜 三明张 等.纳米氧化铝改性聚四氟乙烯的摩擦磨损蛙能研究[J].工程塑料应用,2010,38(2):59-62.
    [12]Burris D L, Zhao S, Duncan R, et al.A route to wear resistant PTFE via trace loadings of functionalized nanofillers [ J ] .Wear, 2009,267 ( 1-4 ) : 653-460.
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